Low-temperature reactions of some atomic ions with molecules of large quadrupole moment: C6F6 and c -C6H12
Identifieur interne : 000317 ( France/Analysis ); précédent : 000316; suivant : 000318Low-temperature reactions of some atomic ions with molecules of large quadrupole moment: C6F6 and c -C6H12
Auteurs : C. Rebrion [France] ; J. B. Marquette [France] ; B. R. Rowe [France] ; N. G. Adams [Royaume-Uni] ; D. Smith [Royaume-Uni]Source :
- Chemical Physics Letters [ 0009-2614 ] ; 1986.
Abstract
Reactions of He+,C+ and N+ ions with C6F6, and c-C6H6 were examined at 27, 68 and 297 K using both CRESU and SIFT techniques. Within the experimental uncertainties, all of the rate coefficients are found to be temperature-independent in this range. The results are discussed in relation to the most recent theoretical models describing the influence of the quadrupole moment on the temperature dependence of ion-molecule reaction rate coefficients.
Url:
DOI: 10.1016/0009-2614(87)80505-5
Affiliations:
- France, Royaume-Uni
- Angleterre, Midlands de l'Ouest, Île-de-France
- Birmingham, Meudon Principal
- Université de Birmingham
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<front><div type="abstract" xml:lang="en">Reactions of He+,C+ and N+ ions with C6F6, and c-C6H6 were examined at 27, 68 and 297 K using both CRESU and SIFT techniques. Within the experimental uncertainties, all of the rate coefficients are found to be temperature-independent in this range. The results are discussed in relation to the most recent theoretical models describing the influence of the quadrupole moment on the temperature dependence of ion-molecule reaction rate coefficients.</div>
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