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Low-temperature reactions of some atomic ions with molecules of large quadrupole moment: C6F6 and c -C6H12

Identifieur interne : 000317 ( France/Analysis ); précédent : 000316; suivant : 000318

Low-temperature reactions of some atomic ions with molecules of large quadrupole moment: C6F6 and c -C6H12

Auteurs : C. Rebrion [France] ; J. B. Marquette [France] ; B. R. Rowe [France] ; N. G. Adams [Royaume-Uni] ; D. Smith [Royaume-Uni]

Source :

RBID : ISTEX:94CD41F011B8C1DA4D9371893CCEAAE464A36DB5

Abstract

Reactions of He+,C+ and N+ ions with C6F6, and c-C6H6 were examined at 27, 68 and 297 K using both CRESU and SIFT techniques. Within the experimental uncertainties, all of the rate coefficients are found to be temperature-independent in this range. The results are discussed in relation to the most recent theoretical models describing the influence of the quadrupole moment on the temperature dependence of ion-molecule reaction rate coefficients.

Url:
DOI: 10.1016/0009-2614(87)80505-5


Affiliations:


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ISTEX:94CD41F011B8C1DA4D9371893CCEAAE464A36DB5

Le document en format XML

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   |texte=   Low-temperature reactions of some atomic ions with molecules of large quadrupole moment: C6F6 and c -C6H12
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